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A REACTIVE CAP FOR CONTAMINATED SEDIMENTS AT THE NAVY'S DODGE POND SITEGavaskar, A., S. Chattopadhyay, M. Hackworth, and V. Lal (Battelle, Columbus, OH); B. Sugiyama (NFESC, Port Hueneme, CA); P. Randall (U.S. EPA, Cincinnati, OH). Partners in Environmental Technology Technical Symposium & Workshop, 29 November - 1 December 2005, Washington, DC: Abstracts. Poster presentation No 66, p F-46, 2005
Caps made from reactive materials can present an innovative solution to
the problems involved in capping contaminated sediments. Contaminants trying
to migrate through a reactive cap will be sorbed, chemically bound, and/or
degraded by the reactive material and thus prevented from being released to
the water column. Many reactive materials currently being considered have one
or more of the following limitations: the materials are too expensive, they
are too selective for the multi-pollutant environment prevalent in most
contaminated sediments, the reactive materials themselves are toxic to aquatic
organisms, or the materials have a low specific gravity and do not settle
effectively as a cap. The authors have tested the use of natural minerals,
such as ores of aluminum, iron, and manganese, for capping contaminated
sediments. A relatively inexpensive mineral, bauxite (aluminum ore), has
emerged as the most promising reactive material. In extensive tests with water
and sediment from different sources, bauxite effectively sequestered a broad
range of contaminants, including mercury, chromium, arsenic, cadmium, nickel,
and zinc, as well as certain organic pollutants. Sequestration of these
contaminants was relatively unaffected by interferences, such as competing
ions and natural organic matter. In toxicity tests, the bauxite proved
non-toxic to benthic amphipods, zooplankton, and fish. With joint funding from
DoD's Environmental Security Technology Program and EPA's Superfund Innovative
Technology Evaluation Program, and with cooperation from the Navy's
Engineering Field Activity North East, a field demonstration of this
technology is planned to remediate mercury-contaminated sediment at the Navy's
Dodge Pond Site in Connecticut. This poster presents the results of
bench-scale work and site-specific treatability tests conducted with Dodge
Pond sediment.
The Technology Innovation News Survey welcomes your comments and
suggestions, as well as information about errors for correction. Please
contact Michael Adam of the U.S. EPA Office of Superfund Remediation
and Technology Innovation at adam.michael@epa.gov or (703) 603-9915
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Mention of non-EPA documents, presentations, or papers does not constitute a U.S. EPA endorsement of their contents, only an acknowledgment that they exist and may be relevant to the Technology Innovation News Survey audience.